SACHEM 提供四丁基氟化铵 (TBAF) 作为具有以下特点的三水合物晶体：：
- 具有最低含水量（每摩尔 TBAF 只含有 3 摩尔水）
- 易溶于有机溶剂，以便增加在各种反应系统中的反应性
- “无水”氟化物源（在溶剂中溶解和进行干燥时），以便于获得
- 适用于碱催化反应的非亲核碱
- 适用于 TBDMS（叔丁基二甲基氯硅烷）的强脱甲硅基剂 – 受保护的醇类
应用：
TBAF 产品供货情况：
我们遍布全球的生产基地和无缝的后勤支持可持久可靠地在世界各地供应各种数量的 TBAF。
- 大批量的商业规模制造能力
- TBAF 三水合物使用 25 kg 和 50 kg 的纸桶包装
白皮书：
TBAF 的综合效用下载白皮书
可选产品
四丁基氟化铵 (TBAF) 三水合物，98%
CAS# 87749-50-6
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所选的关于四丁基氟化铵的文章和专利
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[toggle title=”Click here for selected articles and patents on tetrabutylammonium fluoride.”]
1.Adam, M. J.; Jivan, S.; Huser, J. M.; Lu, J. (2000).11C-methylations using 11C-methyl iodide and tetrabutylammonium fluoride.Radiochimica Acta (2000), 88(3-4), 207-209.
2.Bartsch, Richard (1970) .Eliminations from 2-butyl halides induced by halide ions in dimethylformamide and dimethyl sulfoxide.Journal of Organic Chemistry 35(4), 1023-5.
3.Crawley, Seth and Funk, Raymond.(2006).Generation of Aza-ortho-xylylenes via Ring Opening of 2-(2- Acylaminophenyl)aziridines:Application in the Construction of the Communesin Ring System.Organic Letters 8(18), 3995-3998.
4.Dahlstedt, Emma; Hellberg, Jonas; Petoral, Rodrigo M., Jr.; Uvdal, Kajsa (2004 Synthesis of tetrathiafulvalenes suitable for self-assembly applications.Journal of Materials Chemistry, 14(1), 81-85.
5.Denmark, Scott E; Pan, Weitao.(2003).Intramolecular Syn and Anti Hydrosilylation and Silicon-Assisted Cross-Coupling:Highly Regio- and Stereoselective Synthesis of Trisubstituted Allylic Alcohols.Organic Letters 5(7), 1119-1122.
6.Hojo, Makoto; Ishibashi, Naruyasu; Hosomi, Akira(1994).Heteroarylthiomethylsilanes.Synthesis and application to heteroarylthiomethylation of carbonyl compounds.Heteroatom Chemistry 5(3), 229-34.
7.Lyapkalo, Ilya M.; Webel, Matthias; Reissig, Hans-Ulrich (2001).Enantioselective synthesis of cyclohexenylalkenes by asymmetric deprotonation of 4-tert-butylcyclohexanone followed by O-nonaflation and Heck couplings.Synlett (8), 1293-1295.
8.Muratam Miki; Ohara, Hiroya; Oiwa, Ryo; Watanabe, Shinji; Masuda,Yuzuru (2006).Palladium(0)-catalyzed silylation of aryl halides with triorganosilanes: synthesis of aryl(2-furyl)silanes.Synthesis, (11), 1771-1774.
9.Ogawa, Toshihisa; Hatayama, Katsuo; Maeda, Hiroshi; Kita, Yasuyuki (1994).Mild and facile cleavage of 2-cyanoethyl ester using sodium sulfide or tetrabutylammonium fluoride.Synthesis of 1,4-dihydropyridine monocarboxylic acids and unsymmetrical 1,4-dihydropyridine dicarboxylates.Chemical Pharmaceutical Bulletin 42(8), 1579-89.
10.Ozasa, Nobuko; Wadamoto, Manabu; Ishihara, Kazuaki; Yamamoto, Hisashi (2003).Aldol synthesis with an aqueous solution of formalin.Synlett (14), 2219-2221.
11.Robins, Morris J.; Sarker, Sanchita; Samano, Vicente;.Wnuk, Stanislaw F (1997).Nucleic acid related compounds.94.Remarkably high stereoselective reductions of 2′- and 3′-keto nucleosides to give arabino, ribo, and xylofuranosyl nucleosides with hydrogen isotopes at C2′ and C3′.Tetrahedron 53(2), 447-456.
12.Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro (2004).Cross-coupling of triallyl(aryl)silanes with aryl bromides and chlorides:An alternative convenient biaryl synthesis.Advanced Synthesis Catalysis 346(13-15), 1715-1727.
13.Shan, Daxian ; Zheng, Ailian; Ballard, C. Eric; Wang, Wei;.Borchardt, Ronald T; Wang, Binghe (2000).A facilitated cyclic ether formation and its potential application in solid-phase peptide and organic synthesis.Chemical Pharmaceutical Bulletin (2000), 48(2), 238-244.
14.Sekine, Mitsuo; Yamada, Takeshi; Saneyoshi, Hisao; Seio, Kohji (2007).World Patent 2007/102581.Preparation of 2′-Hydroxyl-Modified Ribonucleoside Derivative.World Patent Office.
15.Sharma, G. V. M.; Reddy, V. Goverdhan; Chander, A. Subhash; Reddy, K. Ravinder (2002) Tetra-n-butylammonium fluoride: an efficient base for aza-Michael addition-synthesis of glycosyl b-amino acid esters.Tetrahedron:Asymmetry 13(1), 21-24.
16.Shiba, Yoshinobu (2007).World Patent 2007/099896.Method For Detaching Protecting Group On Nucleic Acid.World Patent Office.
17.Stawinski, Jacek; Stroemberg, Roger; Thelin, Mats; Westman, Erik (1988).Studies on the t-butyldimethylsilyl group as 2′-O-protection in oligoribonucleotide synthesis via the H-phosphonate approach.Nucleic Acids Research 16(19), 9285-98.
18.Tejero, Ismael; Huertas, Imma; Gonzalez-Lafont, Angels; Lluch, Jose M.; Marquet, Jordi (2005).A Fast Radical Chain Mechanism in the Polyfluoroalkoxylation of Aromatics through NO2 Group Displacement.Mechanistic and Theoretical Studies.Journal of Organic Chemistry 70(5), 1718-1727.
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