SACHEM은 테트라부틸암모늄 불화물(TBAF)을 다음 기능을 제공하는 3수화물 결정체로 제공합니다.
- 최소 함수량(TBAF의 각 몰에 대해 물의 3몰만)
- 다양한 반응 시스템에서 반응성 증가를 위해 유기 용제에서 쉽게 용해
- 접근성 증가를 위한 불소의 “무수” 소스(용제에서 용해되고 건조될 때)
- 염기 촉매 반응에 사용하기 위한 비친핵성 염기
- TBDMS (터트-부틸디메틸클로로실란)-보호 알코올을 위한 강력한 디실리레이션 시약
응용 분야:
TBAF 사용 가능한 제품:
시설과 완벽한 물류 지원의 글로벌 네트워크는 전세계 어디서나 일관성 있고 안정적이고 다양한 수량으로 TBAF를 지원할 수 있습니다.
- 대량으로 상용 규모 제조 능력
- TBAF 3수화물 25kg 및 50kg 섬유 드럼 포장
백서:
TBAF의 종합 유틸리티백서 다운로드
사용 가능한 제품
TBAF(테트라부틸암모늄 불화물) 3수화물, 98%
CAS# 87749-50-6
[sachem_product:433]
해당 응용 분야 요구에 대해 당사와 상담하길 원하십니까? 당사에 문의하십시오.
테트라부틸암모늄 불화물의 선택된 기사 및 특허
[toggle_container keep_open=”false” initial_open=””]
[toggle title=”Click here for selected articles and patents on tetrabutylammonium fluoride.”]
1. Adam, M. J.; Jivan, S.; Huser, J. M.; Lu, J. (2000).11C-methylations using 11C-methyl iodide and tetrabutylammonium fluoride. Radiochimica Acta (2000), 88(3-4), 207-209.
2. Bartsch, Richard (1970) . Eliminations from 2-butyl halides induced by halide ions in dimethylformamide and dimethyl sulfoxide. Journal of Organic Chemistry 35(4), 1023-5.
3. Crawley, Seth and Funk, Raymond. (2006). Generation of Aza-ortho-xylylenes via Ring Opening of 2-(2- Acylaminophenyl)aziridines: Application in the Construction of the Communesin Ring System. Organic Letters 8(18), 3995-3998.
4. Dahlstedt, Emma; Hellberg, Jonas; Petoral, Rodrigo M., Jr.; Uvdal, Kajsa (2004 Synthesis of tetrathiafulvalenes suitable for self-assembly applications. Journal of Materials Chemistry, 14(1), 81-85.
5. Denmark, Scott E; Pan, Weitao. (2003). Intramolecular Syn and Anti Hydrosilylation and Silicon-Assisted Cross-Coupling: Highly Regio- and Stereoselective Synthesis of Trisubstituted Allylic Alcohols.Organic Letters 5(7), 1119-1122.
6. Hojo, Makoto; Ishibashi, Naruyasu; Hosomi, Akira(1994). Heteroarylthiomethylsilanes. Synthesis and application to heteroarylthiomethylation of carbonyl compounds. Heteroatom Chemistry 5(3), 229-34.
7. Lyapkalo, Ilya M.; Webel, Matthias; Reissig, Hans-Ulrich (2001). Enantioselective synthesis of cyclohexenylalkenes by asymmetric deprotonation of 4-tert-butylcyclohexanone followed by O-nonaflation and Heck couplings. Synlett (8), 1293-1295.
8. Muratam Miki; Ohara, Hiroya; Oiwa, Ryo; Watanabe, Shinji; Masuda,Yuzuru (2006).Palladium(0)-catalyzed silylation of aryl halides with triorganosilanes: synthesis of aryl(2-furyl)silanes. Synthesis, (11), 1771-1774.
9. Ogawa, Toshihisa; Hatayama, Katsuo; Maeda, Hiroshi; Kita, Yasuyuki (1994). Mild and facile cleavage of 2-cyanoethyl ester using sodium sulfide or tetrabutylammonium fluoride. Synthesis of 1,4-dihydropyridine monocarboxylic acids and unsymmetrical 1,4-dihydropyridine dicarboxylates. Chemical Pharmaceutical Bulletin 42(8), 1579-89.
10. Ozasa, Nobuko; Wadamoto, Manabu; Ishihara, Kazuaki; Yamamoto, Hisashi (2003).Aldol synthesis with an aqueous solution of formalin. Synlett (14), 2219-2221.
11. Robins, Morris J.; Sarker, Sanchita; Samano, Vicente;.Wnuk, Stanislaw F (1997). Nucleic acid related compounds. 94. Remarkably high stereoselective reductions of 2′- and 3′-keto nucleosides to give arabino, ribo, and xylofuranosyl nucleosides with hydrogen isotopes at C2′ and C3′. Tetrahedron 53(2), 447-456.
12. Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro (2004). Cross-coupling of triallyl(aryl)silanes with aryl bromides and chlorides: An alternative convenient biaryl synthesis. Advanced Synthesis Catalysis 346(13-15), 1715-1727.
13. Shan, Daxian ; Zheng, Ailian; Ballard, C. Eric; Wang, Wei;. Borchardt, Ronald T; Wang, Binghe (2000). A facilitated cyclic ether formation and its potential application in solid-phase peptide and organic synthesis. Chemical Pharmaceutical Bulletin (2000), 48(2), 238-244.
14. Sekine, Mitsuo; Yamada, Takeshi; Saneyoshi, Hisao; Seio, Kohji (2007). World Patent 2007/102581. Preparation of 2′-Hydroxyl-Modified Ribonucleoside Derivative. World Patent Office.
15. Sharma, G. V. M.; Reddy, V. Goverdhan; Chander, A. Subhash; Reddy, K. Ravinder (2002) Tetra-n-butylammonium fluoride: an efficient base for aza-Michael addition-synthesis of glycosyl b-amino acid esters. Tetrahedron: Asymmetry 13(1), 21-24.
16. Shiba, Yoshinobu (2007). World Patent 2007/099896. Method For Detaching Protecting Group On Nucleic Acid. World Patent Office.
17. Stawinski, Jacek; Stroemberg, Roger; Thelin, Mats; Westman, Erik (1988). Studies on the t-butyldimethylsilyl group as 2′-O-protection in oligoribonucleotide synthesis via the H-phosphonate approach. Nucleic Acids Research 16(19), 9285-98.
18. Tejero, Ismael; Huertas, Imma; Gonzalez-Lafont, Angels; Lluch, Jose M.; Marquet, Jordi (2005). A Fast Radical Chain Mechanism in the Polyfluoroalkoxylation of Aromatics through NO2 Group Displacement. Mechanistic and Theoretical Studies. Journal of Organic Chemistry 70(5), 1718-1727.
[/toggle]
[/toggle_container]
